N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV)

Lee, S.M. and Ng, S.W. and Ali, Hapipah Mohd and Lo, K.M. (2009) N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 65. M1689-U1615. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809050107.

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Abstract

The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)degrees. Intramolecular O-H center dot center dot center dot N hydrogen bonding is present in the crystal structure.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	05 Apr 2013 01:51
Last Modified:	31 Jan 2019 04:37
URI:	http://eprints.um.edu.my/id/eprint/5368

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