Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1)

Lee, S.M. and Robinson, W.T. and Ali, Hapipah Mohd and Lo, K.M. (2009) Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1). Acta Crystallographica Section E: Structure Reports Online, 65. N1039-U291. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809030232.

Preview

PDF Lee-2009-Bis_4-(dimethylamino.pdf - Published Version Download (346kB)

Abstract

In the title compound, (C7H11N2)(2)[SnBr4(C6H4Cl)(2)]center dot-C6H4BrCl, the Sn-IV atom in the tetrabromidobis(4-chlorophenyl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethylamino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) angstrom, suggesting weak hydrogen bonding. The 4-bromochlorobenzene solvent molecule, which is a bromination by-product from the reaction, is disordered about a twofold rotation axis with approximately equal occupancy.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	03 Apr 2013 03:50
Last Modified:	29 Jan 2019 08:52
URI:	http://eprints.um.edu.my/id/eprint/5355

Actions (login required)

View Item