Lee, S.M. and Robinson, W.T. and Ali, Hapipah Mohd and Lo, K.M. (2009) Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O '. Acta Crystallographica Section E: Structure Reports Online, 65. M808-U1140. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809023150.
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Abstract
The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Miss Malisa Diana |
| Date Deposited: | 04 Apr 2013 01:38 |
| Last Modified: | 29 Jan 2019 08:39 |
| URI: | http://eprints.um.edu.my/id/eprint/5354 |
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