Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate

Halim, S.N.A. and Ng, S.W. and Ali, Hapipah Mohd (2010) Bis N '-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N ',O ' manganese(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M1439-U950. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810039516.

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Abstract

In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110].

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 02:24
Last Modified: 29 Jan 2019 09:08
URI: http://eprints.um.edu.my/id/eprint/5307

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