3,4,5-Trihydroxy-N '-(1H-indol-2-yl-methylidene)benzohydrazide-1H-indole-2-carbaldehyde azine-methanol (2/1/2)

Khaledi, Hamid and Alhadi, Abeer A. and Ali, Hapipah Mohd and Robinson, Ward T. and Abdulla, Mahmood A. (2010) 3,4,5-Trihydroxy-N '-(1H-indol-2-yl-methylidene)benzohydrazide-1H-indole-2-carbaldehyde azine-methanol (2/1/2). Acta Crystallographica Section E: Structure Reports Online, E66. o105-o106. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809052465.

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Abstract

The title compound, 2C(16)H(13)N(3)O(4)center dot C(18)H(14)N(4)center dot 2CH(4)O, was crystallized from the reaction between 3,4,5-trihydroxy-benzoylhydrazine and indole-2-carbaldehyde in a mixture of ethanol and methanol. The compound is a stoichiometric 2:1 cocrystal of the methanol-solvated reaction product, 3,4,5-trihydroxy-N'-(1H-indol-2-ylmethylidene) benzohydrazide and 1H-indole-2-carbaldehyde azine that arose unexpectedly during the synthesis. The former molecules are linked by O-H center dot center dot center dot O hydrogen bonds and also by pi-pi stacking interactions between benzoylhydrazide rings into a two-dimensional network. The methanol solvent molecules are hydrogen bonded to this network. The centrosymmetric azine molecules are not engaged in hydrogen bonding.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Gallic Acid; Derivatives
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry Faculty of Medicine
Depositing User:	Miss Malisa Diana
Date Deposited:	01 Apr 2013 04:09
Last Modified:	11 Nov 2019 03:26
URI:	http://eprints.um.edu.my/id/eprint/5302

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