Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV)

Khaledi, H. and Abdulla, M.A. and Ali, Hapipah Mohd (2010) Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M351-U184. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810007014.

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Abstract

The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 02:21
Last Modified: 29 Jan 2019 09:10
URI: http://eprints.um.edu.my/id/eprint/5301

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