Bis mu-4-hydroxy-N '-(4-methoxy-2-oxidobenzylidene)benzohydrazidato bis pyridinecopper(II)

Lair, N.M. and Puteh, R. and Ali, Hapipah Mohd and Khaledi, H. (2010) Bis mu-4-hydroxy-N '-(4-methoxy-2-oxidobenzylidene)benzohydrazidato bis pyridinecopper(II). Acta Crystallographica Section E: Structure Reports Online, 66. M470-U1240. ISSN 1600-5368

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In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine molecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 angstrom). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O interactions and also O-H center dot center dot center dot N hydrogen bonds.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 27 Mar 2013 07:49
Last Modified: 29 Jan 2019 09:09

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