3,4,5-Trihydroxybenzohydrazidium perchlorate-3,4,5-trihydroxybenzohydrazide-water (1/1/1)

Alhadi, A.A. and Ali, Hapipah Mohd and Khaledi, H. (2011) 3,4,5-Trihydroxybenzohydrazidium perchlorate-3,4,5-trihydroxybenzohydrazide-water (1/1/1). Acta Crystallographica Section E: Structure Reports Online, 67. O2229-U1687. ISSN 1600-5368

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Official URL: http://scripts.iucr.org/cgi-bin/paper?S16005368110...

Abstract

The crystal studied of the title compound, C7H9N2O4+center dot ClO4-center dot-C7H8N2O4 center dot H2O, was found to be a racemic twin with a 0.72 (18):0.28 (18) domain ratio. The hydrazidium group is close to planar, with an r.m.s deviation of 0.105 angstrom; the hydrazide group deviates more from planarity, with an r.m.s deviation of 0.174 angstrom. In the crystal, the hydrazidium cation, hydrazide molecule, perchlorate anions and water molecules are linked through O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds into a three-dimensional supramolecular network. In addition, the benzene rings of the hydrazidium and hydrazide units are connected via pi-pi interactions into infinite chains along the c axis; the centroid-centroid distances are 3.486 (3) and 3.559 (3) angstrom.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 26 Mar 2013 01:25
Last Modified: 30 Jan 2019 01:11
URI: http://eprints.um.edu.my/id/eprint/5259

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