Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II). Acta Crystallographica Section E: Structure Reports Online. M205-U885. ISSN 1600-5368

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Official URL: http://scripts.iucr.org/cgi-bin/paper?S16005368110...

Abstract

In the title complex, [Co(NCS)(2)(C13H19N3O)(H2O)], the Co-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot S, C-H center dot center dot center dot S and S center dot center dot center dot S [3.5546 (18) angstrom] interactions result in an infinite three-dimensional network.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Mar 2013 02:19
Last Modified: 30 Jan 2019 01:02
URI: http://eprints.um.edu.my/id/eprint/5256

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