Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)nickel(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 67. M108-U1116. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810052578.

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Abstract

In the title compound, [Ni(NCS)(2)(C13H19N3O)(H2O)], the Ni-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, O-H center dot center dot center dot S, O-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds link adjacent molecules into layers parallel to the ac plane.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	26 Mar 2013 01:22
Last Modified:	30 Jan 2019 01:03
URI:	http://eprints.um.edu.my/id/eprint/5255

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