Catena-Poly {N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa(3) N,N ',N ''}(thiocyanato-kappa N)cadmium -mu-thiocyanato-kappa(2) S:N

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Catena-Poly {N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa(3) N,N ',N ''}(thiocyanato-kappa N)cadmium -mu-thiocyanato-kappa(2) S:N. Acta Crystallographica Section E: Structure Reports Online, 67. M480-U835. ISSN 1600-5368

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In the title compound, [Cd(NCS)(2)(C11H17N3)] (n) , the CdII atom is octahedrally coordinated by the N,N',N''-tridentate Schiff base ligand and one terminal thiocyanate N atom. Two trans-N:S-bridging thiocyanates complete the N5S donor set around the Cd atom. In the crystal, adjacent CdII ions are linked by the thiocyanate N:S-bridges into polymeric chains along the c axis.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 26 Mar 2013 00:17
Last Modified: 30 Jan 2019 01:06

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