Aquachloridobis(2-{ 3-(morpholin-4-yl)propyl iminomethyl}phenolato)manganese(III) monohydrate

Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. (2011) Aquachloridobis(2-{ 3-(morpholin-4-yl)propyl iminomethyl}phenolato)manganese(III) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 67. M1044-U460. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811026493.

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Abstract

In the title compound, [Mn(C14H19N2O2)(2)Cl(H2O)]center dot H2O, the Mn-III atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O-H center dot center dot center dot N, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network through C-H center dot center dot center dot O interactions.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	25 Mar 2013 02:01
Last Modified:	30 Jan 2019 01:01
URI:	http://eprints.um.edu.my/id/eprint/5233

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