Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc

Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc. Acta Crystallographica Section E: Structure Reports Online, 67. M932-U1048. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022021.

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Abstract

In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 22 Mar 2013 01:59
Last Modified: 30 Jan 2019 00:55
URI: http://eprints.um.edu.my/id/eprint/5232

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