Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) pyridine disolvate

Khaledi, H. and Ali, Hapipah Mohd (2011) Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) pyridine disolvate. Acta Crystallographica Section E: Structure Reports Online, E67. M230. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811001991.

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Abstract

The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)degrees. The indole NH groups are bonded to the pyridine solvent molecules via an N-H center dot center dot center dot N interaction. The crystal structure is consolidated by intermolecular C-H center dot center dot center dot S interactions.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Key indicators: single-crystal X-ray study; T = 100 K; mean � (C–C) = 0.005 A ̊; R factor = 0.039; wR factor = 0.070; data-to-parameter ratio = 14.8
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	25 Mar 2013 01:56
Last Modified:	30 Jan 2019 01:05
URI:	http://eprints.um.edu.my/id/eprint/5223

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