Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) N,N-dimethylformamide disolvate

Khaledi, H. and Ali, Hapipah Mohd (2011) Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) N,N-dimethylformamide disolvate. Acta Crystallographica Section E: Structure Reports Online, 67. M84-U905. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810051780.

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Abstract

In the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, formin g a five-membered ring with the metal atom. The Pd-II ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethylformamide (DMF) solvent molecules via an N-H center dot center dot center dot O interaction. In addition, C-H center dot center dot center dot S interactions are observed.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	25 Mar 2013 01:53
Last Modified:	30 Jan 2019 01:05
URI:	http://eprints.um.edu.my/id/eprint/5222

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