Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium). Acta Crystallographica Section E: Structure Reports Online, 67. M251-U1438. ISSN 1600-5368

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Abstract

In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry about each Cd-II atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) angstrom.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Ligands
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 21 Mar 2013 02:01
Last Modified: 30 Jan 2019 00:54
URI: http://eprints.um.edu.my/id/eprint/5210

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