Enhanced thermoelectric properties of Bi1.92Li0.08Sr2Co2Oy x wt% SiC composites

Park, K. and Hong, H. Y. and Gwon, S. Y. and Jeon, E. C. and Sabri, M. F. M. (2025) Enhanced thermoelectric properties of Bi1.92Li0.08Sr2Co2Oy x wt% SiC composites. Inorganic Chemistry Communications, 171. p. 113596. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2024.113596.

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Official URL: https://doi.org/10.1016/j.inoche.2024.113596

Abstract

In this work, Bi1.92Li0.08Sr2Co2Oy/x wt% SiC (1.0 <= x <= 4.0 wt%) composites are fabricated through a solid-state reaction followed by spark plasma sintering. The resulting composites exhibit plate-like grains and high density. The addition of SiC nanoparticles reduces electrical conductivity due to decreased hole mobility and increases the Seebeck coefficient due to an enhanced scattering factor and effective mass. Furthermore, the incorporation of SiC nanoparticles significantly enhances phonon scattering, thereby reducing phonon thermal conductivity. The Bi1.92Li0.08Sr2Co2Oy/2.0 wt% SiC composite exhibits the largest ZT of 0.17 at 973 K due to its high Seebeck coefficient and low thermal conductivity. Our results demonstrate that incorporating SiC nanoparticles is a highly effective strategy for enhancing the thermoelectric properties of Bi1.92Li0.08Sr2Co2Oy.

Item Type: Article
Funders: Ministry of Environment (ME), Republic of Korea
Uncontrolled Keywords: Energy; Climate change; Spark plasma sintering; Composites; Seebeck coefficient; Thermoelectric properties
Subjects: T Technology > TJ Mechanical engineering and machinery
Divisions: Faculty of Engineering > Department of Mechanical Engineering
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 17 Mar 2025 05:00
Last Modified: 17 Mar 2025 05:00
URI: http://eprints.um.edu.my/id/eprint/47228

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