Alamier, Waleed M. and Tasneem, Shadma and Nabi, Arshid and Hasan, Nazim and Nabi, Firdosa (2022) Thermodynamic and spectroscopic studies of SDS in cinnamaldehyde plus ethanol mixtures: Influences of temperature and composition. Applied Sciences-Basel, 12 (23). ISSN 2076-3417, DOI https://doi.org/10.3390/app122312020.
Full text not available from this repository.Abstract
The study of intermolecular interactions between ethanol (E-OH), cinnamaldehyde (CAD) with anionic surfactant sodium dodecyl sulfate (SDS) in non-aqueous media has been examined by utilizing conductometric and spectroscopic techniques. The critical micelle concentration (CMC) values have been determined. The experimental conductance data were analyzed against temperature and concentration using standard relations. The pseudo phase separation model has been adopted to calculate various thermodynamic parameters like standard free energy, increment G degrees(mic), enthalpy, increment H degrees(mic), and entropy, increment S degrees(mic), of micelle formation. Fourier transforms infrared analysis (FTIR), and Fluorescence spectra were taken out to assess the possible interactions prevailing in the micellar systems. The findings demonstrated that the presence of SDS, and the composition of CAD + ethanol might affect the thermodynamic parameters. The discrepancy in these parameters with the surfactant concentration or with the temperature change indicates the manifestation of different interactions prevailing in the studied systems.
| Item Type: | Article |
|---|---|
| Funders: | Deanship of Scientific Research, Jazan University [RUP2-02] |
| Uncontrolled Keywords: | ethanol; CAD; thermodynamic parameters; CMC; hydrophobic-hydrophobic interactions; FTIR analysis |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms Koh Ai Peng |
| Date Deposited: | 06 Nov 2024 08:40 |
| Last Modified: | 06 Nov 2024 08:40 |
| URI: | http://eprints.um.edu.my/id/eprint/46124 |
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