Advance Heteroatom Dopants Nitrogen, Boron, Sulphur, and Phosphorus on Carbon Dots towards Histamine Detection in Fish Sample

Fahmi, Mochamad Zakki and Sugito, Siti Febtria Asrini and Hanifah, Nadia Aulia and Nur'aini, Ummi Lathifah and Purwanto, Bambang and Voon, Lee Hwei (2024) Advance Heteroatom Dopants Nitrogen, Boron, Sulphur, and Phosphorus on Carbon Dots towards Histamine Detection in Fish Sample. Sains Malaysiana, 53 (2). pp. 347-358. ISSN 0126-6039, DOI https://doi.org/10.17576/jsm-2024-5302-09.

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Official URL: https://doi.org/10.17576/jsm-2024-5302-09

Abstract

This study introduces heteroatom-doped carbon dots (CDs), namely boron-sulphur (BS-CDs) and nitrogenphosphorus (NP-CDs), highlighting their potential as optical materials for sensitive histamine detection in sensor applications. Synthesized through facile pyrolysis of citric acid cores with non-metal dopants, resulting in confirmed graphene-like structures and uniform spheres with crystal diameters below 3 nm of BS-CDs and NP-CDs. The optical properties exhibited blue fluorescence, with emission wavelengths of 280 nm (QY 0.08%) and 420 nm (QY 1.72%) for BS-CDs and NP-CDs, respectively. Despite declined fluorescence intensities due to interfering components, both CDs demonstrated low selectivity for histamine, which increased the intensity in its presence. Notably, BS-CDs exhibited superior detectability of histamine at a low concentration of 26.3 ppm compared to 42.8 ppm for NP-CDs. Cytotoxicity studies indicated low toxicity for both CDs, positioning them as promising candidates for further development as histamine detectors

Item Type: Article
Funders: RKI Republic Indonesia (563/UN 3.14/LT/2018)
Uncontrolled Keywords: Boron; carbon dots; co-dopants; histamine detector; nitrogen; phosphorus; sulphur
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 08 Nov 2024 07:07
Last Modified: 08 Nov 2024 07:07
URI: http://eprints.um.edu.my/id/eprint/45678

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