Sadiq, Niyaz M. and Abdulwahid, Rebar T. and Aziz, Shujahadeen B. and Woo, Haw Jiunn and Kadir, Mohd Fakhrul Zamani (2024) Chitosan as a suitable host for sustainable plasticized nanocomposite sodium ion conducting polymer electrolyte in EDLC applications: Structural, ion transport and electrochemical studies. International Journal of Biological Macromolecules, 265 (1). p. 130751. ISSN 0141-8130, DOI https://doi.org/10.1016/j.ijbiomac.2024.130751.
Full text not available from this repository.Abstract
The challenge in front of EDLC device is their low energy density compared to their battery counter parts. In the current study, a green plasticized nanocomposite sodium ion conducting polymer blend electrolytes (PNSPBE) was developed by incorporating plasticized Chitosan (CS) blended with polyvinyl alcohol (PVA), doped with NaBr salt with various concentration of CaTiO3 nanoparticles. The most optimized PNSPBE film was subsequently utilized in an EDLC device to evaluate its effectiveness both as an electrolyte and a separator. Structural and morphological changes were assessed using XRD and SEM techniques. The PNSPBE film demonstrated a peak ionic conductivity of 9.76 x 10-5 S/cm, as determined through EIS analysis. The dielectric and AC studies provided further confirmation of structural modifications within the sample. Both TNM and LSV analyses affirmed the suitability of the prepared electrolyte for energy device applications, evidenced by its adequate ion transference number and an electrochemical potential window of 2.86 V. Electrochemical properties were assessed via CV and GCD techniques, confirming non-Faradaic ion storage, indicated by the rectangular CV pattern at low scan rates. The parameters associated with the designed EDLC device including specific capacitance, ESR, power density (1950 W/kg) and energy density (12.3 Wh/kg) were determined over 1000 cycles.
| Item Type: | Article |
|---|---|
| Funders: | Universiti Malaya, University of Sulaimani Iraq, University of Cihan Sulaimaniya |
| Uncontrolled Keywords: | Nanocomposite polymer electrolyte; Electrochemical impedance spectroscopy; XRD; EDLC; Nanoparticles |
| Subjects: | Q Science > QC Physics |
| Divisions: | Faculty of Science > Department of Physics |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 16 Oct 2024 07:40 |
| Last Modified: | 16 Oct 2024 07:40 |
| URI: | http://eprints.um.edu.my/id/eprint/45415 |
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