Wang, Jian and Shao, Yachuan and Ma, Yanqiang and Zhang, Di and Aziz, Shujahadeen B. and Li, Zhaojin and Woo, Haw Jiunn and Subramaniam, Ramesh T. and Wang, Bo (2024) Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy. ACS Nano, 18 (14). pp. 10230-10242. ISSN 1936-0851, DOI https://doi.org/10.1021/acsnano.4c00599.
Full text not available from this repository.Abstract
The realization of sodium-ion devices with high-power density and long-cycle capability is challenging due to the difficulties of carrier diffusion and electrode fragmentation in transition metal selenide anodes. Herein, a Mo/W-based metal-organic framework is constructed by a one-step method through rational selection, after which MoWSe/C heterostructures with large angles are synthesized by a facile selenization/carbonization strategy. Through physical characterization and theoretical calculations, the synthesized MoWSe/C electrode delivers obvious structural advantages and excellent electrochemical performance in an ethylene glycol dimethyl ether electrolyte. Furthermore, the electrochemical vehicle mechanism of ions in the electrolyte is systematically revealed through comparative analyses. Resultantly, ether-based electrolytes advantageously construct stable solid electrolyte interfaces and avoid electrolyte decomposition. Based on the above benefits, the Na half-cell assembled with MoWSe/C electrodes demonstrated excellent rate capability and a high specific capacity of 347.3 mA h g(-1) even after cycling 2000 cycles at 10 A g(-1). Meanwhile, the constructed sodium-ion capacitor maintains similar to 80% capacity retention after 11,000 ultralong cycles at a high-power density of 3800 W kg(-1). The findings can broaden the mechanistic understanding of conversion anodes in different electrolytes and provide a reference for the structural design of anodes with high capacity, fast kinetics, and long-cycle stability.
| Item Type: | Article |
|---|---|
| Funders: | National Natural Science Foundation of China (NSFC) (FRGS/1/2022/STG05/UM/02/3), Ministry of Education, Malaysia (22008053); (52002111), National Natural Science Foundation of China (NSFC) (B2021208061); (B2022208006), Natural Science Foundation of Hebei Province (JZX2024025), Science Foundation of University of Hebei Province (ST089-2022), Universiti Malaya |
| Uncontrolled Keywords: | MoWSe/C electrode; heterostructures; electrolytes; structure design; sodium-ion devices |
| Subjects: | Q Science > Q Science (General) Q Science > QC Physics |
| Divisions: | Faculty of Science > Department of Physics |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 21 Oct 2024 02:57 |
| Last Modified: | 21 Oct 2024 02:57 |
| URI: | http://eprints.um.edu.my/id/eprint/45403 |
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