Novel polyamide-hydrazide based reverse osmosis membrane with enhanced antifouling properties

Wang, Zhongyang and Akram, Muhammad Adnan and Zhang, Shanshan and Gong, Jingwei and Zhao, Lihua and Liu, Zhiyu and Niu, Q. Jason (2024) Novel polyamide-hydrazide based reverse osmosis membrane with enhanced antifouling properties. Desalination, 574. ISSN 1873-4464, DOI https://doi.org/10.1016/j.desal.2023.117233.

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Official URL: https://doi.org/10.1016/j.desal.2023.117233

Abstract

The typical ``ridge-valley'' structure of traditional reverse osmosis (RO) membranes ensures good permeability with high risk of inducing membrane fouling. It is a challenge to develop a smooth RO membrane without loss of permeability. In this study, cyclobutane-1,2,3,4-tetracarbohydrazide (CBTH) was designed and synthesized, and a composite RO membrane based on CBTH and cyclobutane-1,2,3,4-tetracarboxylic acid chloride (BTC) was constructed. The CBTH-BTC membrane exhibits a smooth selective layer with thickness of 45 nm. The desalination performance test results show that the CBTH-BTC membrane has permeability and desalination performance comparable to the traditional RO membrane (the water permeability coefficient reaches 3.0 L & sdot;m(- 2)& sdot;h(- 1)& sdot;bar(-1), and the rejection of NaCl reaches 99.2 %). Importantly, the hydrophilic and smooth surface imparts the membrane with good antifouling properties to hydrophilic, hydrophobic and surfactant pollutants. In this study, RO membranes with good permeability and excellent antifouling performance were successfully prepared from the perspective of reaction monomer design, which provides a new idea to regulate the morphology and antifouling properties of RO membranes.

Item Type: Article
Funders: National Natural Science Foundation of China (NSFC) [U2006230], National Natural Science Foundation of China (NSFC) [52103120], Shenzhen Science and Technology Foundations [JCYJ20210324095202008], Shenzhen Science and Technology Foundations [20220807153901001] JCYJ20210324095202008, Science and Technology Innovation Strategy Project of Guangdong Province [STKJ202209015], Guangdong-Shenzhen Joint Fund of Guangdong Province [2021A1515110707]
Uncontrolled Keywords: Reverse osmosis membrane; Antifouling; Novel monomer; Polyamide-hydrazide; Morphology control
Subjects: T Technology > TD Environmental technology. Sanitary engineering
T Technology > TP Chemical technology
Divisions: Faculty of Engineering > Department of Chemical Engineering
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 21 Jun 2024 06:36
Last Modified: 21 Jun 2024 06:36
URI: http://eprints.um.edu.my/id/eprint/44219

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