Ecofriendly zinc oxide-decorated poly-3-hydroxyalkanoate-graft-poly-methyl acrylate copolymer film for photocatalysis-mediated water treatment

Ishak, Khairul Anwar and Safian, Nur Azmina Mohamed and Annuar, Mohamad Suffian Mohamad (2022) Ecofriendly zinc oxide-decorated poly-3-hydroxyalkanoate-graft-poly-methyl acrylate copolymer film for photocatalysis-mediated water treatment. Journal of Polymers and the Environment, 30 (4). pp. 1662-1672. ISSN 1566-2543, DOI https://doi.org/10.1007/s10924-021-02307-y.

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Abstract

The application of microbiologically produced polymer, i.e., medium-chain-length poly-3-hydroxyalkanoate (mcl-PHA), in environmental remediation technology was investigated. Mcl-PHA and its graft copolymer, polyhydroxyalkanoate-g-polymethylacrylate (PHA-g-PMA), were used as the supporting matrices to hold zinc oxide microparticles (ZnO MPs). The polymer composites, i.e., neat PHA/ZnO and PHA-g-PMA/ZnO, were tested as the catalytic support materials to enhance photodegradation of an organic dye, i.e., methylene blue (MB). PHA-g-PMA/ZnO film composite yields a significant MB photodegradation compared to the neat PHA/ZnO composite. Photodegradation performance was investigated as MB removal percentage (%) and rate constant of photocatalysis reaction (k). The enhanced photocatalytic performance in PHA-g-PMA is discussed.

Item Type: Article
Funders: Ministry of Higher Education, Malaysia (MOHE) [Grant No; FP038-2020], Universiti Malaya, Institut Pengurusan dan Pemantauan Penyelidikan, Universiti Malaya [Grant No; IIRG017A-2019, UM.C/625/1/HIR/MOHE/05]
Uncontrolled Keywords: Biological polymer; Poly-3-hydroxyalkanoate (PHA); Graft copolymer; Photocatalysis; Water remediation
Subjects: Q Science > Q Science (General)
Q Science > QH Natural history > QH301 Biology
Divisions: Faculty of Science > Institute of Biological Sciences
Deputy Vice Chancellor (Research & Innovation) Office
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 11 Oct 2023 08:09
Last Modified: 11 Oct 2023 08:09
URI: http://eprints.um.edu.my/id/eprint/42424

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