L-cysteine grafted fiber-optic chemosensor for heavy metal detection

Ooi, C. W. and Waldo, U. and Yusoff, Norazriena and Lim, Kok Sing and Tan, S. T. and Zakaria, Rozalina and Ahmad, H. (2022) L-cysteine grafted fiber-optic chemosensor for heavy metal detection. Optical Fiber Technology, 71. ISSN 1068-5200, DOI https://doi.org/10.1016/j.yofte.2022.102938.

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Abstract

In this work, we have demonstrated metal ion detection using L-Cysteine functionalised gold-coated tilted fiber Bragg grating (Au-TFBG). L-cysteine (L-cys) is a semi-essential amino acid that has high tendency to form Au-S bond via thiol group on the gold surface of the sensor whereas the amine groups and carboxyl groups of the L-cys molecules can serve as surface ligands that bind with the metal ions in the test analyte. The findings indicate that the sensor was reactive and sensitive to different metal ions including Co2+, Cd2+, Cu2+, Pb2+, Ni2+ and Zn2+. By adopting the two-step procedure in the measurement, the refractive index noise can be effectively discriminated from the signal and the functionality of the L-cysteine grafted Au-TFBG sensor can be validated. The selectivity test results show that the sensor has high affinity towards Cu2+ metal ion and the measured LOD is 0.19 mu M.

Item Type: Article
Funders: University of Malaya, Impact-Oriented Interdisciplinary Research Grant (IIRG) (Grant No: llRG028A-2019)
Uncontrolled Keywords: L-Cysteine; Surface plasmon resonance; Tilted fiber Bragg grating; Metal ion
Subjects: T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Photonics Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 16 Oct 2023 01:55
Last Modified: 16 Oct 2023 01:55
URI: http://eprints.um.edu.my/id/eprint/42184

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