Synthesis, functionalization and coordination chemistry of dibenzotetraaza14]annulenes

Ramle, Abdul Qaiyum and Tiekink, Edward R. T. and Basirun, Wan Jefrey (2022) Synthesis, functionalization and coordination chemistry of dibenzotetraaza14]annulenes. Coordination Chemistry Reviews, 469. ISSN 00108545, DOI https://doi.org/10.1016/j.ccr.2022.214672.

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Abstract

This comprehensive review summarizes recent advances in the synthesis and coordination chemistry of dibenzotetraaza14]annulenes (DBTAAs) reported between 2010 and 2021. Owing to the smaller N4 donor cavity compared to that of the porphyrin core, it is not surprising that DBTAA offers versatile and unique coordination modes towards metal ions. The structural modification of the DBTAA core allows for the fine-tuning of their spectroscopic properties. DBTAA and derivatives have been utilized across a wide range of research disciplines such as in electronic devices and biological assays. The feasible preparation of ligands and their metal complexes suggests DBTAAs as potential alternatives to porphyrins. (c) 2022 Elsevier B.V. All rights reserved.

Item Type: Article
Funders: Sunway University Sdn Bhd (Grant No: GRTIN-RRO-56-2022)
Uncontrolled Keywords: DBTAA; Core-functionalization; Coordination chemistry; Spectroscopic properties
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 20 Oct 2023 02:36
Last Modified: 20 Oct 2023 02:36
URI: http://eprints.um.edu.my/id/eprint/41848

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