Visible light-enable oxidation and antibacterial of zinc oxide hybrid chitosan photocatalyst towards aromatic compounds treatment

Mohd Adnan, Mohd Azam and Phoon, Bao Lee and Johan, Mohd Rafie and Tajaruddin, Husnul Azan and Muhd Julkapli, Nurhidayatullaili (2022) Visible light-enable oxidation and antibacterial of zinc oxide hybrid chitosan photocatalyst towards aromatic compounds treatment. Materials Today Communications, 32. ISSN 2352-4928, DOI 0.1016/j.mtcomm.2022.103956.

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Abstract

A solar-driven, ZnO-supported chitosan (ZnO/CS) photocatalyst has been formulated, with the aim of enhanced photocatalytic activities with a simple acidic mixing process and the gel solidification method. ZnO/CS, with a narrow band gap (2.89 eV) and macro-porous structure was confirmed under Ultra Violet Diffuse Reflection Spectra (UV DRS) and Transmission Electron Microscopy (TEM), respectively. The Field Emission Scanning Electron Microscopy (FESEM) revealed that average bead size of 100-250 mu m of the photocatalyst with ZnO stayed in the hexagonal phase, dispersed, and embedded into CS. The adsorption and photocatalyst activity of the hybrid catalyst was investigated regarding the composition of the catalyst, catalyst dosage, pH of the solution, and concentration of the solution. The catalyst with a composition of 2:1 (ZnO/CS) demonstrates the optimum decolarization properties. Catalytic performances were recorded at up to 89% photodecolarization at pH 12 with 10 ppm of methylene blue under visible irradiation. This has brought a new approach for a highly efficient, stable, sustainable, and low-cost dye water treatment technology.

Item Type: Article
Funders: Nippon Sheet Foundation, IF002-2022, Selangor Research Grant, Malaysia, GPNS/01/UNI-SEL/18-047
Uncontrolled Keywords: Photocatalyst; Support materials; Biopolymer; Metal oxide
Subjects: Q Science > QD Chemistry
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Nov 2023 08:52
Last Modified: 22 Nov 2023 08:52
URI: http://eprints.um.edu.my/id/eprint/41609

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