Perovskite zinc titanate-reduced graphene oxide nanocomposite photoanode for improved photovoltaic performance in dye-sensitized solar cell

Sasikala, R. and Kandasamy, M. and Ragavendran, V. and Suresh, S. and Sasirekha, V. and Murugesan, S. and Sagadevan, Suresh and Mayandi, Jeyanthinath (2022) Perovskite zinc titanate-reduced graphene oxide nanocomposite photoanode for improved photovoltaic performance in dye-sensitized solar cell. Physica B-Condensed Matter, 646. ISSN 0921-4526, DOI https://doi.org/10.1016/j.physb.2022.414300.

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Abstract

The current generation of solar cells are playing a predominant role in energy storage industries due to their economic cost, abundant, and compact design for photovoltaic applications. In this context, composite materials based on perovskite zinc titanate nanoparticles (ZnTiO3 NPs) and perovskite zinc titanate-reduced graphene oxide nanocomposite (RGO-ZnTiO3 NC) were prepared by a simple sol-gel technique. The ZnTiO3 NPs and RGO-ZnTiO3 NC were subjected to X-ray diffraction analysis for calculating crystal structure, crystallite size, microstrain, and dislocation density. The band gap energy of the ZnTiO3 NPs and RGO-ZnTiO3 NCs was found to be 2.9 and 3.1 eV, respectively. X-ray photoelectron spectroscopy was used to determine elemental species of the RGO-ZnTiO3 NC. The photovoltaic performance of the dye-sensitized solar cell (DSSC) with RGO-ZnTiO3 NC photoanode exhibited strong dye adsorption to facilitate considerable light absorption and efficient electron transport, due to less surface trapping sites compared to unmodified ZnTiO(3)NPs photoanode based DSSC. The RGO-ZnTiO3 NC photoanode demonstrated best photovoltaic performance with a short-circuit current density of 4.27 mA cm(-2) and better photoelectric conversion efficiency of 1.11%, which is similar to 2.6 folds higher than the DSSC with ZnTiO3 NPs photoanode.

Item Type: Article
Funders: RUSA MKU [002/RUSA/MKU/2020-2021Dt]
Uncontrolled Keywords: RGO-ZnTiO3 nanocomposite; Perovskite photoanode; Dye-sensitized solar cell; Photovoltaic performance
Subjects: Q Science > QC Physics
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 07 Sep 2023 03:01
Last Modified: 07 Sep 2023 03:01
URI: http://eprints.um.edu.my/id/eprint/41119

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