Green synthesis and characterization of copper oxide nanoparticles and their photocatalytic activity

Koteeswari, P. and Sagadevan, Suresh and Fatimah, Is and Sibhatu, Assefu Kassegn and Razak, Saiful Izwan Abd and Leonard, Estelle and Soga, Tetsuo (2022) Green synthesis and characterization of copper oxide nanoparticles and their photocatalytic activity. Inorganic Chemistry Communications, 144. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2022.109851.

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Abstract

Copper Oxide (CuO) nanoparticles were synthesized through a green approach using the papaya and banana peel reducing as well as a stabilizing agents and copper (II) nitrate trihydrate salt as a precursor. The sample was characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Scanning electron microscope (SEM), Transmission electron microscope (TEM), and UV???visible diffuse reflectance spectroscopy (DRS). The characterization results revealed about the CuO NPs structure, shape, energy gap, and functional group variations. The energy band-gap was calculated to be 1.92 (papaya peel extract), and 1.22 eV (banana peel extract), respectively. Under visible light irradiation, the photocatalytic activity of CuO NPs was investigated by degrading Methylene blue (MB) dye. It depicts that synthesized CuO NPs have a great potential for application as a photocatalyst to degrade textile colours in wastewater treatment in a short period. Moreover, the pseudo-firstorder reaction rate constants were found to be 0.00359 min-1 (papaya peel extract) and 0.00335 min-1 (banana peel extract), respectively.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: CuO; Nanoparticles; Green synthesis; Optical and photocatalytic activity
Subjects: Q Science > QD Chemistry
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 25 Aug 2023 04:10
Last Modified: 25 Aug 2023 04:10
URI: http://eprints.um.edu.my/id/eprint/40925

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