Capacity determination of ZnCo0.26O1.63-N0.18C0.82 derived from bimetallic zeolitic imidazolate framework as anode in sodium-ion battery

Imaduddin, I. S. and Majid, S. R. and Kamaruddin, N. S. and Yusoff, N. F. M. and Idris, N. H. (2022) Capacity determination of ZnCo0.26O1.63-N0.18C0.82 derived from bimetallic zeolitic imidazolate framework as anode in sodium-ion battery. Journal of Materials Science: Materials in Electronics, 33 (33). pp. 25263-25273. ISSN 0957-4522, DOI https://doi.org/10.1007/s10854-022-09233-2.

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Abstract

A bimetallic Zn-Co-ZIF derived from metal organic framework was successfully synthesized via simple co-precipitation method. The as-synthesized bimetallic MOF powder was then pyrolyzed at 600 degrees C, 700 degrees C, 800 degrees C, and 900 degrees C in N-2 atmosphere, which changed the morphology and structure of the final product evidenced from field emission scanning electron microscopy and X-ray diffraction. The electrochemical results revealed that the change in elemental composition affected the specific capacity, cycling stability, and rate capability for each sample. The galvanostatic charge-discharge results showed that C600 achieved the highest specific capacity and rate capability compared to other samples heated at higher temperatures. On the other hand, C900, the sample heated at the highest temperature exhibited the best capacity retention after 50 cycles at 78% after the initial discharge whilst providing the lowest reversible discharge capacity at 45 mAh g(-1).

Item Type: Article
Funders: Ministry of Education, Malaysia, Universiti Malaya FRGS/1/2018/STG07/UM/02/8, SATU Joint Research Grant ST033-2020
Uncontrolled Keywords: Lithium ion; Performance; Carbon
Subjects: Q Science > QC Physics
Divisions: Faculty of Science > Department of Physics
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 04 Nov 2025 12:42
Last Modified: 04 Nov 2025 12:42
URI: http://eprints.um.edu.my/id/eprint/40791

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