Zaharani, Lia and Johan, Mohd Rafie and Khaligh, Nader Ghaffari (2022) Cost and energy saving process for the laboratory-scale production of chloroform-d. Organic Process Research and Development, 26 (11). pp. 3126-3129. ISSN 1083-6160, DOI https://doi.org/10.1021/acs.oprd.2c00260.
Full text not available from this repository.Abstract
Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone with deuterium oxide (D2O) in the presence of poly(N-vinylimidazole). The catalyst is more sustainable, highly recyclable, highly chemical and thermally stable, soluble in D2O, and high in efficiency.
| Item Type: | Article |
|---|---|
| Funders: | Universiti Malaya, Malaysia (Grant No: ST018- 2022 & RU003-2021) |
| Uncontrolled Keywords: | Sustainable chemistry; Catalysis; Polymer; NMR solvent; One-pot synthesis |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Nanotechnology & Catalysis Research Centre |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 22 Nov 2023 07:14 |
| Last Modified: | 22 Nov 2023 07:14 |
| URI: | http://eprints.um.edu.my/id/eprint/40382 |
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