Fabrication and characterization of Si/PEDOT: PSS-based heterojunction solar cells

Venkatesan, Ragavendran and Sheik Kadar Maideen, Sheik Moideen Thaha and Chandhiran, Saravanan and Kushvaha, Sunil Singh and Sagadevan, Suresh and Venkatachalapathy, Vishnukanthan and Mayandi, Jeyanthinath (2022) Fabrication and characterization of Si/PEDOT: PSS-based heterojunction solar cells. Electronics, 11 (24). ISSN 2079-9292, DOI https://doi.org/10.3390/electronics11244145.

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Abstract

In this study, we fabricated a planar Si/PEDOT: PSS heterojunction solar cell using three different solvents-ethylene glycol, acetonitrile, and dimethyl sulfoxide-to find the best one. The fabricated samples were characterized by diffuse reflectance spectroscopy, scanning electron microscopy, X-ray diffraction, and current-voltage. Diffused reflectance spectrum analysis showed reduced reflectance compared to the bare silicon wafers. The absorbance spectrum shows the change in absorption of the Si-coated PEDOT: PSS which was more than a 50% increase in the UV region, and for the EG sample, there was a 20% increase in the entire visible spectrum. This indicates that the solvent plays a major role in the bandgap between the Si and Si/PEDOT: PSS. Scanning electron microscope (SEM) was used to examine the surface morphology of Si/PEDOT: PSS as agglomerated, island-formed surfaces and carbon-layered Si-PEDOT: PSS. Cross-sectional images show the thickness of the PEDOT: PSS layer on the silicon wafer surface. The X-ray diffraction (XRD) pattern shows the characteristic peaks for silicon (69.5 degrees), and Si/PEDOT: PSS shows a forbidden Si (200) peak at 32 degrees. Current-voltage measurements have shown the characteristic diode curve for all fabricated cells. This characteristic diode curve indicated the presence of a heterojunction. Ethylene glycol-containing cells showed current output as 0.2 mu A with V-oc of 0.2 V.

Item Type: Article
Funders: CSIR-RA (Grant No: 09/201(0424)/19-EMR-1)
Uncontrolled Keywords: Silicon; PEDOT; PSS; Heterojunction; Reflectance; Solar cell; Organic solvents
Subjects: Q Science > QC Physics
T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 23 Nov 2023 03:51
Last Modified: 23 Nov 2023 03:51
URI: http://eprints.um.edu.my/id/eprint/40316

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