3D flower-like FeWO4/CeO(2)hierarchical architectures on rGO for durable and high-performance microalgae biophotovoltaic fuel fells

Karthikeyan, C. and Rani, G. Jenita and Ng, Fong-Lee and Periasamy, Vengadesh and Pappathi, M. and Rajan, Michael Jothi and Al-Sehemi, Abdullah G. and Pannipara, Mehboobali and Phang, Siew-Moi and Aziz, Md Abdul and Kumar, G. Gnana (2020) 3D flower-like FeWO4/CeO(2)hierarchical architectures on rGO for durable and high-performance microalgae biophotovoltaic fuel fells. Applied Biochemistry and Biotechnology, 192 (3). pp. 751-769. ISSN 0273-2289, DOI https://doi.org/10.1007/s12010-020-03352-4.

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Abstract

A facile chemical reduction approach is adopted for the synthesis of iron tungstate (FeWO4)/ceria (CeO2)-decorated reduced graphene oxide (rGO) nanocomposite. Surface morphological studies of rGO/FeWO4/CeO(2)composite reveal the formation of hierarchical FeWO(4)flower-like microstructures on rGO sheets, in which the CeO(2)nanoparticles are decorated over the FeWO(4)microstructures. The distinct anodic peaks observed for the cyclic voltammograms of studied electrodes under light/dark regimes validate the electroactive proteins present in the microalgae. With the cumulative endeavors of three-dimensional FeWO(4)microstructures, phase effect between rGO sheet and FeWO4/CeO2, highly exposed surface area, and light harvesting property of CeO(2)nanoparticles, the relevant rGO/FeWO4/CeO(2)nanocomposite demonstrates high power and stable biophotovoltaic energy generation compared with those of previous reports. Thus, these findings construct a distinct horizon to tailor a ternary nanocomposite with high electrochemical activity for the construction of cost-efficient and environmentally benign fuel cells.

Item Type: Article
Funders: Council of Scientific and Industrial Research (CSIR), New Delhi-Major Project (01(2997)19/EMR-II), Deanship of Scientific Research at King Khalid University (G.R.P.205-40), Newton Prize Grant 2017 (IF008-2018), Higher Institution Centre of Excellence (HICoE) Fund, Ministry of Education, Malaysia: Air, ocean and land interaction (IOES-2014F)
Uncontrolled Keywords: Microflower; Ternary nanocomposite; Microalgae; Biophotovoltaic fuel cell; Green energy
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Institute of Biological Sciences
Faculty of Science > Department of Physics
Deputy Vice Chancellor (Research & Innovation) Office > Institute of Ocean and Earth Sciences
Depositing User: Ms Zaharah Ramly
Date Deposited: 07 Mar 2023 03:25
Last Modified: 07 Mar 2023 03:25
URI: http://eprints.um.edu.my/id/eprint/37609

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