M. Hadi, Jihad and B. Aziz, Shujahadeen and M. Nofal, Muaffaq and Hussein, Sarkawt A. and Hafiz, Muhamad H. and Brza, Mohamad A. and Abdulwahid, Rebar T. and woohj@um.edu.my, Abdul Kadir and Woo, Haw Jiunn (2020) Electrical, Dielectric Property and Electrochemical Performances of Plasticized Silver Ion-Conducting Chitosan-Based Polymer Nanocomposites. Membranes, 10 (7). ISSN 2077-0375, DOI https://doi.org/10.3390/membranes10070151.
Full text not available from this repository.Abstract
In the present work, chitosan (CS) as a natural biopolymer was used to prepare nanocomposite polymer electrolytes (NCPEs) in order to reduce plastic waste pollution. The plasticized CS-based NCSPE has been prepared via the solution casting technique. The electrical properties of the films were investigated using AC conductivity, dielectric properties, electric modulus, and electrical impedance spectroscopy (EIS). The obtained results from the dielectric properties and electric modulus study confirm the non-Debye behavior of ion dynamics. The effect of glycerol plasticizer on ionic conductivity of the CS:AgNO3:Al(2)O(3)system was investigated via AC conductivity and impedance studies. The conductivity of the samples was explained based on electrical equivalent circuits and Bode plots. The electrochemical properties such as transfer number measurement (TNM), linear sweep voltammetry (LSV), and cyclic voltammetry (CV) were carried out to inspect the sample suitability for electrochemical double-layer capacitor (EDLC) application. The highest conductivity was 3.7 x 10(-4)S cm(-1)with the electrochemical stability window up to 2.1 V at room temperature. Through the TNM study, the ionic conductivity of plasticized CS-based NCSPE was confirmed, and ion transport (t(ion)) of the highest conducting sample was found to be 0.985. The activated carbon electrode with the highest conducting sample was employed in the EDLC device fabrication. Accordingly, it can be said that the highest conducting sample had capable performance to be applied in electrochemical device application.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Polymer electrolyte; Al(2)O(3)nano-filler; AC conductivity; Impedance study; Dielectric properties; TNM and LSV; EDLC |
| Subjects: | Q Science > Q Science (General) Q Science > QC Physics |
| Divisions: | Centre for Foundation Studies in Science Centre for Foundation Studies in Science > Physics Division Faculty of Science Faculty of Science > Department of Physics |
| Depositing User: | Ms Zaharah Ramly |
| Date Deposited: | 31 Dec 2023 03:16 |
| Last Modified: | 31 Dec 2023 03:16 |
| URI: | http://eprints.um.edu.my/id/eprint/36583 |
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