Kittappa, Shanmuga and Jang, Min and Ramalingam, Malarvili and Ibrahim, Shaliza (2020) Amine functionalized magnetic nano-composite materials for the removal of selected endocrine disrupting compounds and its mechanism study. Journal of Environmental Chemical Engineering, 8 (4). ISSN 22133437, DOI https://doi.org/10.1016/j.jece.2020.103839.
Full text not available from this repository.Abstract
A novel adsorbent successfully synthesized using recyclable silica, nano magnetite and N1-(3 trimethoxisilylpropyl) diethylenetriamine (TRIS) denoted as MNCMT. Three endocrine disrupting compounds (EDCs) such as bisphenol A (BPA), ibuprofen (IBP) and clorofibric acid (CFA) were selected as model drugs for this study. The sorption capacities of EDCs by MNCMT were found to be 182.6 mg g(-1) for BPA, followed by CFA at 101.8 mg g(-1) and 72.6 mg g(-1) for IBP. The removal process matched with Langmuir isotherm and pseudo second order kinetic models with determination coefficient (R-2) above 0.99. The adsorbent was regenerated, recovered and reused for multiple cycles of adsorption. The physical-chemical properties and experimental data revealed that the chemical sorption is more dominant than physical sorption. Hydrogen bonding, pi-pi and electrostatic attractions provide intrinsic information on the removal mechanism.
| Item Type: | Article |
|---|---|
| Funders: | Universiti Malaya (Grant No. RP 19A-13AET, RP008C-14SUS, RU 0030-2017) |
| Uncontrolled Keywords: | Magnetic adsorbent; EDCs; TRIS coated; Isotherm; Kinetic; Mechanism |
| Subjects: | Q Science > QC Physics |
| Divisions: | Deputy Vice Chancellor (Research & Innovation) Office > Institute of Ocean and Earth Sciences |
| Depositing User: | Ms Zaharah Ramly |
| Date Deposited: | 30 Dec 2023 16:13 |
| Last Modified: | 30 Dec 2023 16:13 |
| URI: | http://eprints.um.edu.my/id/eprint/36515 |
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