An electrochemical evaluation of synthesized coumarin-Azo dyes as potential corrosion inhibitors for mild steel in 1 M HCl medium

Yusoff, Mohd Hamizi and Azmi, Mohamad Nurul and Hussin, Mohd Hazwan and Osman, Hasnah and Raja, Pandian Bothi and Rahim, Afidah Abdul and Awang, Khalijah (2020) An electrochemical evaluation of synthesized coumarin-Azo dyes as potential corrosion inhibitors for mild steel in 1 M HCl medium. International Journal of Electrochemical Science, 15 (12). pp. 11742-11756. ISSN 1452-3981, DOI https://doi.org/10.20964/2020.12.43.

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Abstract

The anti corrosion properties of mild steel were studied in 1.0 M HCl medium with azo-coumarin dyes inhibitor by electrochemical impedance and potentiodynamic polarization measurements. The azo-coumarin dyes 8-10 were synthesized by coupling reaction between diazonium salt of aniline derivatives with 4-hydroxycoumarin under basic condition. The result showed that inhibition efficiency was found to increase (shown average IE > 80%), with increasing the concentration of azocoumarin dyes, and their adsorption over mild steel surface found to obey Langmuir adsorption isotherm. Furthermore, the Langmuir adsorption isotherm parameters made evident that corrosion inhibition proceeds through physisorption mode of interaction. After corrosion evaluation, mild steel's surface morphology was screened via SEM - EDX analysis which showed an improved surface in the presence of azo-coumarin dye derivatives.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Corrosion inhibitor; Azo-coumarin dyes; Mild steel; Electrochemical impedance
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science
Faculty of Science > Department of Chemistry
Depositing User: Ms Zaharah Ramly
Date Deposited: 29 Nov 2023 07:22
Last Modified: 29 Nov 2023 07:22
URI: http://eprints.um.edu.my/id/eprint/36250

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