Dual role of Magnesium as a catalyst and precursor with enriched boron in the synthesis of Magnesium diboride nanoparticles

Ahmad, Pervaiz and Khandaker, Mayeen Uddin and Jamil, Saliha and Rehman, Fida and Muhammad, Nawshad and Ullah, Zahoor and Khan, M. Abdul Rauf and Khan, Ghulamullah and Alotaibi, Mshari A. and Alharthi, Abdulrahman and Din, Israf Ud and Hussain, Fayyaz and Khan, M. Imtiaz and Ali, Hazrat (2020) Dual role of Magnesium as a catalyst and precursor with enriched boron in the synthesis of Magnesium diboride nanoparticles. CERAMICS INTERNATIONAL, 46 (17). pp. 26809-26812. ISSN 02728842, DOI https://doi.org/10.1016/j.ceramint.2020.07.156.

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Abstract

Nano-scale powder of Magnesium (Mg) is found to play the dual role of catalyst and precursor with Boron-10 (B-10) in the synthesis of Magnesium diboride nanoparticles (Mg(10)B(2)NPs) at 800 degrees C. Catalytically, Mg softens and melts enriched Boron at a relatively lower temperature than its actual boiling point. As a precursor, it reacts with enriched Boron and forms the (MgB2)-B-10 compound. The nano-size catalyst and precursors help to grow the as-formed (MgB2)-B-10 compound in the form of nanoparticles. The shape or morphology of the synthesized Mg(10)B(2)NPs is revealed via field emission scanning electron microscopy (FESEM). Energy dispersive x-ray (EDX) spectroscopy has been performed to spot the elemental composition, whereas, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) are used to verify the composition and study the phase of the synthesized particles.

Item Type: Article
Funders: Prince Sattam Bin Abdulaziz University Saudi Arabia, University of Azad Jammu and Kashmir Pakistan, University of Malaya Malaysia
Uncontrolled Keywords: Magnesium; Catalyst; Dual-role; Precursor; Nanomaterials
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Physics
Depositing User: Ms Zaharah Ramly
Date Deposited: 28 Dec 2023 06:17
Last Modified: 28 Dec 2023 06:17
URI: http://eprints.um.edu.my/id/eprint/36195

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