Sea-to-air fluxes of isoprene and monoterpenes in the coastal upwelling region of Peninsular Malaysia

Uning, Royston and Latif, Mohd Talib and Abd Hamid, Haris Hafizal and Nadzir, Mohd Shahrul Mohd and Khan, Md Firoz and Suratman, Suhaimi (2021) Sea-to-air fluxes of isoprene and monoterpenes in the coastal upwelling region of Peninsular Malaysia. ACS Earth and Space Chemistry, 5 (12). pp. 3429-3436. ISSN 2472-3452, DOI https://doi.org/10.1021/acsearthspacechem.1c00270.

Full text not available from this repository.

Abstract

Volatile organic compounds (VOCs) affect oxidant loadings and secondary organic aerosol formation in the lower atmosphere. The marine environment is thought to be an important global source of biogenic VOCs (BVOCs). Despite that, there is relatively limited knowledge on coastal upwelling BVOCs. This paper presents sea-to-air fluxes and spatial and temporal distributions of the BVOCs, isoprene and monoterpenes, in the coastal upwelling region off the east coast of Peninsular Malaysia (ECPM). The overall fluxes Coastline ranged between 10(7) and 10(8) molecules/cm(2)/s, which is comparable with open ocean values. Isoprene dominated the overall fluxes with an average percentage of 65% compared to monoterpenes (total) (35%). Among the monoterpene Upwelling compounds, beta-pinene showed the highest average flux, followed by alpha-pinene and limonene. The spatial distribution suggests that isoprene fluxes potentially correspond to the sea surface water nutrients compared to monoterpenes. A significant relationship between isoprene and monoterpene (total) fluxes was observed (R = 0.73, P < 0.01), which may indicate that both isoprene and monoterpenes are controlled by an identical biological factor (e.g., chlorophyll-a). This study concludes that the upwelling region off the ECPM is potentially an important source of atmospheric isoprene and monoterpenes.

Item Type: Article
Funders: Malaysian Ministry of Science, Technology, and Innovation (MOSTI) E-Science Fund[04-01-02-SF1259], Ministry of Higher Education (MOHE) through the Higher Institution Centre of Excellence (HICoE) Research Grant[66928]
Uncontrolled Keywords: Biogenic volatile organic compounds;Floating flux chamber;TD-GC-MS;Spatial;Temporal;Coastal waters
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Q Science > QE Geology
Depositing User: Ms Zaharah Ramly
Date Deposited: 18 Oct 2022 04:18
Last Modified: 18 Oct 2022 04:18
URI: http://eprints.um.edu.my/id/eprint/35269

Actions (login required)

View Item View Item