(E,E)-1,2-Bis[4-(prop-2-yn-1-yl-oxy)benzyl-idene]hydrazine.

Al-Mehana, W.N.; Yahya, R.; Lo, K.M. (2011) (E,E)-1,2-Bis[4-(prop-2-yn-1-yl-oxy)benzyl-idene]hydrazine. Acta Crystallogr Sect E Struct Rep Online., 67 (pt11).

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    Abstract

    The mol-ecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric with the mid-point of the central N-N bond located on an inversion center. The configuration around the C=N bond is E. The whole mol-ecule (except for the H atoms) is approximately planar, with an r.m.s. deviation of 0.07 Å. In the crystal, the presence of weak inter-molecular C-H⋯O hydrogen bonding involving each acetyl-ene H atom and the adjacent phen-oxy O atom results in the formation of supra-molecular chains.

    Item Type: Article
    Creators:
    1. Al-Mehana, W.N.
    2. Yahya, R.
    3. Lo, K.M.(University of Malaya)
    Journal or Publication Title: Acta Crystallogr Sect E Struct Rep Online.
    Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia Correspondence e-mail: kmlo@um.edu.my
    Uncontrolled Keywords: Key indicators: single-crystal X-ray study; T = 100 K; mean �(C–C) = 0.001 A˚; R factor = 0.037; wR factor = 0.111; data-to-parameter ratio = 16.3.
    Subjects: Q Science > QD Chemistry
    R Medicine
    Divisions: Faculty of Science > Dept of Chemistry
    Depositing User: Mr. Faizal Hamzah
    Date Deposited: 04 Jul 2012 08:45
    Last Modified: 04 Jul 2012 08:45
    URI: http://eprints.um.edu.my/id/eprint/3465

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