Yeo , C.I.; Tiekink , E.R. (2011) 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph. Acta Crystallogr Sect E Struct Rep Online, 67 (pt11).
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The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho-rhom-bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134-136]. The mol-ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N-H atoms are syn to each other, which contrasts their anti disposition in the ortho-rhom-bic form. In the crystal, mol-ecules assemble into zigzag chains along the c axis via N-H⋯S hydrogen bonds. Chains are connected into layers via C-H⋯Cl inter-actions, and these stack along the a axis.
|Journal or Publication Title:||Acta Crystallogr Sect E Struct Rep Online|
|Additional Information:||Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculty of Science > Dept of Chemistry|
|Depositing User:||Mr. Faizal Hamzah|
|Date Deposited:||03 Jul 2012 15:09|
|Last Modified:||03 Jul 2012 15:09|
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