Utilization of tires waste-derived magnetic-activated carbon for the removal of hexavalent chromium from wastewater

Ahmad, Waqas and Qaiser, Shanif and Ullah, Rahman and Mohamed Jan, Badrul and Karakassides, Michael A. and Salmas, Constantinos E. and Kenanakis, George and Ikram, Rabia (2021) Utilization of tires waste-derived magnetic-activated carbon for the removal of hexavalent chromium from wastewater. Materials, 14 (1). ISSN 1996-1944, DOI https://doi.org/10.3390/ma14010034.

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Abstract

The present study focuses on fabrication of magnetic activated carbon (M-AC) using tire waste and its potential investigation for adsorption of Cr (VI) from wastewater. The composite material (M-AC) was synthesized by pyrolysis followed by in situ magnetization method, and characterized by FTIR, FESEM, EDX, and XRD analysis. The maximum adsorption of Cr (VI) ion over composite adsorbent was found (similar to 99.5%) to occur at pH 2, sample volume 10 mL, adsorbent dose 100 mg, contact time 30 min. The adsorption process was endothermic, feasible, spontaneous, and was found to follow pseudo second order of the reaction. The Cr ion could be completely desorbed (similar to 99.3%) from the composite adsorbent by using 20 mL of 2 M NaOH solution. The composite adsorbent was regenerated by continuous adsorption and desorption for 5 consecutive cycles by using 10 mL 0.1 M HCl solution. M-AC also performed well in case of tannery wastewater by removing about 97% of Cr (VI).

Item Type: Article
Funders: Fundamental Research Grant Scheme [Grant No: FP050-2019A], Malaysia-Thailand Joint Authority [Grant No: IF062-2019], Kejuruteraan Kimia from University of Malaya [Grant No: GPF078A-2018], National Priorities Research Program from the Qatar National Research Fund (member of The Qatar Foundation) [Grant No: NPRP11S-1128-170042], European Commission, Greek Ministry of Development-GSRT [Grant No: T2EDK-02073]
Uncontrolled Keywords: Tire waste; Hexavalent chromium; Magnetic activated carbon; Wastewater treatment; Tannery wastewater
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Faculty of Engineering > Department of Chemical Engineering
Depositing User: Ms Zaharah Ramly
Date Deposited: 20 Jun 2022 06:45
Last Modified: 20 Jun 2022 06:45
URI: http://eprints.um.edu.my/id/eprint/34079

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