Synthesis and characterization of hybrid Molecularly Imprinted Polymer (MIP) membranes for removal of Methylene Blue (MB)

Asman , S.; Yusof , N.A.; Abdullah , A.H.; Haron , M.J. (2012) Synthesis and characterization of hybrid Molecularly Imprinted Polymer (MIP) membranes for removal of Methylene Blue (MB). Molecules, 17 (2). ISSN 1431-5157

Abstract

This work reports the synthesis and characterization of a hybrid molecularly imprinted polymer (MIP) membrane for removal of methylene blue (MB) in an aqueous environment. MB-MIP powders were hybridized into a polymer membrane (cellulose acetate (CA) and polysulfone (PSf)) after it was ground and sieved (using 90 µm sieve). MB-MIP membranes were prepared using a phase inversion process. The MB-MIP membranes were characterized using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM). Parameters investigated for the removal of MB by using membrane MB-MIP include pH, effect of time, concentration of MB, and selectivity studies. Maximum sorption of MB by PSf-MB-MIP membranes and CA-MB-MIP membranes occurred at pH 10 and pH 12, respectively. The kinetic study showed that the sorption of MB by MB-MIP membranes (PSf-MB-MIP and CA-MB-MIP) followed a pseudo-second-order-model and the MB sorption isotherm can be described by a Freundlich isotherm model.

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