Ng, Su Han and Bin Mazlee, Muhammad Taufiq Firdausi and Heidelberg, Thorsten (2021) Biantennary alkyl triazole glycosides by double-click-coupling for water-in-oil-emulsification. Journal of Surfactants and Detergents, 24 (3). pp. 473-482. ISSN 1097-3958, DOI https://doi.org/10.1002/jsde.12511.
Full text not available from this repository.Abstract
A series of biantennary sugar-based surfactants reflecting glyco-glycero-lipids, in which the ester linkage of the surfactant antipodes was replaced by a triazole, has been synthesized and investigated on their emulsifying potential for water-in-oil systems related to hydrofuel. The results suggest beneficial interactions of the triazole with fossil-derived diesel, whereas corresponding interactions appear to destabilize emulsions in ester-based biodiesel. The highest emulsion stability was observed for 1,3-linked glycerol-isomers, where the glucose-based ATG outperformed the corresponding xylose-analogue exhibiting a significantly higher Krafft temperature. Molecular modeling results relate this behavior to chromonic interactions of the triazole rings.
| Item Type: | Article |
|---|---|
| Funders: | Universiti Malaya (RG264-13AFR) (PG161-2015A) |
| Uncontrolled Keywords: | Alkyl triazole glycoside (ATG); Click chemistry; Hydrofuel; Water; Emulsion |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) |
| Divisions: | Faculty of Science |
| Depositing User: | Ms Zaharah Ramly |
| Date Deposited: | 11 Mar 2022 08:49 |
| Last Modified: | 11 Mar 2022 08:49 |
| URI: | http://eprints.um.edu.my/id/eprint/27077 |
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