Quaternary nanorod-type BaInSbSe5 semiconductor combined graphene-based conducting polymer (PPy) nanocomposite and highly sensing performance of H2O2 & H2S gases

Oh, Won-Chun and Lim, Chang Sung and Liu, Yin and Sagadevan, Suresh and Jang, Won Kweon and Biswas, Md Rokon Ud Dowla (2021) Quaternary nanorod-type BaInSbSe5 semiconductor combined graphene-based conducting polymer (PPy) nanocomposite and highly sensing performance of H2O2 & H2S gases. Journal of Materials Science: Materials in Electronics, 32 (12). pp. 15944-15963. ISSN 0957-4522, DOI https://doi.org/10.1007/s10854-021-06145-5.

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Official URL: https://doi.org/10.1007/s10854-021-06145-5

Abstract

Quaternary nanorod-type BaInSbSe5 semiconductor combined graphene-based conducting polymer (PPy) (BaInSbSe5-G-PPy, BNSGP) nanocomposites were prepared using a facile hydrothermal method. BNSGP nanocomposites were used to make up gas sensors to detect H2O2 and H2S at standard temperature condition. Morphologies, shape, and structures of BNSGP were specified by X-ray diffractometer (XRD), Scanning Electron Microscopy (SEM), Energy-dispersive X-ray elemental analyzer (EDX), transmission electron microscopy (TEM), high-resolution TEM (HRTEM) technique, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and diffuse reflectance spectroscopy (DRS). When examined with H2O2 and H2S concentrations as low as 10 ppb, the gas sensor using BNSGP nanocomposites showed a good reactivity and sensitivity of 1.25 V/K with real-time response/recovery effects of 234 and 76 s, respectively. It also showed a conspicuously high selectivity for H2O2 and H2S. However, it only showed insignificant response to any other reactance gases such as HCl, CH3OH, and C2H5OH. Its performance as a H2O2 and H2S sensor was estimated by CV meter (cyclic voltammeter). The fabricated sensor for H2O2 and H2S showed an extensive linear selectivity from 300 to 90 ppm with a low detection range of 300 ppm.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Feb 2022 03:31
Last Modified: 22 Feb 2022 03:31
URI: http://eprints.um.edu.my/id/eprint/26230

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