Synthesis and crystal structures of two infinite molecular ladders Ag(4,4′-bpy)X (X = MeCO2·3H2O or H2PO4·H3PO4): function of hydrogen-bonding interaction

Tong, Ming Liang and Chen, Xiao Ming and Ng, Seik Weng (2000) Synthesis and crystal structures of two infinite molecular ladders Ag(4,4′-bpy)X (X = MeCO2·3H2O or H2PO4·H3PO4): function of hydrogen-bonding interaction. Inorganic Chemistry Communications, 3 (8). pp. 436-441. ISSN 1387-7003

Full text not available from this repository.
Official URL: https://doi.org/10.1016/S1387-7003(00)00116-7

Abstract

Two new ladder motifs of [Ag(4,4'-bpy)](x) (4,4'-bpy = 4,4'-bipyridine) sidepieces that are linked by ligand-supported or ligand-unsupported Ag ··· Ag rungs have been crystallographically documented in [Ag(4,4'-bpy)(μ<SUB2-O2CMe)](n) · 3nH2O 1 and [Ag(4,4'-bpy)](n)(H2PO4)(n) · (H3PO4)(n) 2, respectively; both compounds were synthesized from the self-assembly of silver(I) salts with 4,4'-bpy. The ladders in both complexes are stacked into layers, which are further interconnected by the hydrogen-bonding nets formed by the counterions and water (or H3PO4) molecules, resulting in two three-dimensional networks. (C) 2000 Elsevier Science S.A.

Item Type: Article
Uncontrolled Keywords: Silver(I) compounds; Molecular ladders; Self-assembly; 4,4′-bipyridine
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 12 Apr 2021 02:46
Last Modified: 12 Apr 2021 02:46
URI: http://eprints.um.edu.my/id/eprint/25864

Actions (login required)

View Item View Item