Ng, Seik Weng and Hu, Shengzhi (2000) Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Jiegou Huaxue, 19 (6). pp. 405-410. ISSN 0254-5861,
Full text not available from this repository.Abstract
The space groups of [(CH3CH2)4N]3 {[(SCH2CH2S)MoS3]2Fe} and [(CH3CH2)4N]2 {[S2CN(C2H5)2]4Fe 4S4} are revised from Cc to C2/c by solving the C2/c structure from the structure factors that are calculated from the Cc structure. The structures are both disordered in one of the tetraethylammonium cations. The space group of [(CH3CH2)4N]3 {[(SCH2CH2S)MoS3]2Fe} · 1/4CH3CN is revised from Pc to P21/c; because of the severe disorder in the cations that was not addressed in the original refinements, only the atomic coordinates of the metal-cluster anions could be revised. The space group of [(CH3CH2)4N]3 {[(CH3)2NCS2Cu]2MoS4} · 2CH3CN (originally described in P1̄) is re-assigned to C2/c. The general descriptions of the structures are unchanged in the higher-symmetry settings. The revised coordinates are given.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Mo-Fe(Cu)-S clusters; Simulated intensities; Space-group corrections |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 12 Apr 2021 02:25 |
| Last Modified: | 12 Apr 2021 02:25 |
| URI: | http://eprints.um.edu.my/id/eprint/25859 |
Actions (login required)
 |
View Item |
