Sim, Yoke Leng and Khan, Mohammad Niyaz (2009) Explanation of unusual behaviour in the acidic hydrolytic cleavage of N-(2′-methoxyphenyl)phthalimide under typical reaction conditions. Progress in Reaction Kinetics and Mechanism, 34 (4). pp. 347-359. ISSN 1468-6783, DOI https://doi.org/10.3184/146867809X471117.
Full text not available from this repository.Abstract
Pseudo-first-order rate constants, kobs, for hydrolysis of N-(2′-methoxyphenyl)- phthalimide (1) show a nonlinear decrease with the increase in [HCl] over the range 5×10-3 - 1:0M at 2:0×10-4M 1, 1.0M ionic strength (μ, by NaCl) and 35°C. White fluffy precipitates have been found to appear into the reaction mixtures under such conditions, not at reaction time t = 0 but during the course of reaction. Similar observations have been found at 3:0×10-4M 1. These rather unusual observations have been found to be due to a special NaCl salt effect on kobs. © 2009 Science Reviews 2000 Ltd.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | N-(2'-methoxyphenyl)phthalimide; acidic hydrolysis; NaCl effect; kinetics; mechanism |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 14 Dec 2020 05:44 |
| Last Modified: | 14 Dec 2020 05:44 |
| URI: | http://eprints.um.edu.my/id/eprint/25658 |
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