Bis(μ-N,2-di-3-pyridylisoindoline-1-imine-κ2N,N′)bis[aqua(perchlorato-κO)cadmium(II)] bis(perchlorate) methanol disolvate

Zhu, Li-Na and Gao, Shan and Ng, Seik Weng (2007) Bis(μ-N,2-di-3-pyridylisoindoline-1-imine-κ2N,N′)bis[aqua(perchlorato-κO)cadmium(II)] bis(perchlorate) methanol disolvate. Acta Crystallographica Section E: Structure Reports Online, 63 (10). m2618-m2618. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536807046272.

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Official URL: https://doi.org/10.1107/S1600536807046272

Abstract

The dinuclear dication in the title compound, [Cd2(ClO4)2(C17H14N4)4(H2O)2] (ClO4)2·2CH4O, lies on a twofold rotation axis as the two N,2-di-3-pyridylisoindoline-1-imine N-heterocycles function in 2-bridging modes. Aside from the four N atoms, the Cd atom is also linked to the water and perchlorate O atoms, the O atoms being cis to each other in an octa-hedral geometry. The charge is balanced by two perchlorate ions; these inter-act weakly with the coordinated water and uncoordinated methanol mol-ecules. © International Union of Crystallography 2007.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Phthalimidine; 3-Methyleneisoindolin-1-One; Cyclization
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 10 Aug 2020 06:46
Last Modified: 10 Aug 2020 06:46
URI: http://eprints.um.edu.my/id/eprint/25300

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