Zhang, Xiang-Pei and Yang, Guang and Ng, Seik Weng (2006) 4,4′-Bipyridinium tetrachloroaurate(III) chloride. Acta Crystallographica Section E: Structure Reports Online, 62 (9). m2018-m2020. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536806029199.
Full text not available from this repository.Abstract
The reaction of gold(III) chloride and 4,4′-bipyridine yields the compound (C10H8N2)[AuCl3] 2, which is converted to the ionic title compound (C 10H10N2)[AuCl4]Cl upon recrystallization from DMSO. The AuIII ion in the tetrachloroaurate anion exhibits a square-planar geometry; this anion is linked to the bipyridinium cation by an N-H⋯Cl hydrogen bond to form chains which extend parallel to the b axis. The bipyridinium cation exhibits 2 symmetry, whereas the tetrachloroaurate anion shows 2/m symmetry, and the chloride anion is located on a position with 222 symmetry. © 2006 International Union of Crystallography. All rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Ions; Space; Centers |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 06 Aug 2020 08:24 |
| Last Modified: | 06 Aug 2020 08:24 |
| URI: | http://eprints.um.edu.my/id/eprint/25291 |
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