Zheng, Yan-Zhen and Ng, Seik Weng (2005) catena-Poly[[bis(μ-1,10-phenanthrolin-2-olato-κ3N,N′:O)dicopper(I,II)(Cu—Cu)]-μ-chlorocopper(I)-μ-chloro]. Acta Crystallographica Section E: Structure Reports Online, 61 (6). m1030-m1032. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536805013632.
Full text not available from this repository.Abstract
In the crystal structure of the title compound, [Cu3(C 12H7N2O)2Cl2] n, the mixed-valence CuI/CuII cation and the cuprate(I) anion both lie on centres of inversion. The O atom of one half of the planar N,N′-chelated dinuclear copper cation binds to the Cu atom of the other half; the geometry around the metal atom is square-planar, owing to the symmetry-related metal atom at a distance of 2.3945 (5) Å. The dinuclear cations are bridged through the anions to form an infinite linear chain. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Tautomers; Dione; Ligands |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 06 Aug 2020 08:02 |
| Last Modified: | 06 Aug 2020 08:02 |
| URI: | http://eprints.um.edu.my/id/eprint/25288 |
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