Zhang, Kou-Lin and Pan, Zi-Cai and Chang, Yan and Liu, Wen-Long and Ng, Seik Weng (2009) Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence. Materials Letters, 63 (24-25). pp. 2136-2138. ISSN 0167-577X, DOI https://doi.org/10.1016/j.matlet.2009.05.040.
Full text not available from this repository.Abstract
A new inorganic-organic hybrid lead(II) coordination polymer [PbCl(tza)]n (Htza = tetrazole-1-acetic acid) has been synthesized under hydrothermal condition. The complex was characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray analysis, thermogravimetric analysis (TG) and differential scanning calorimetry thermal analysis (DSC). The Pb(II) centers are connected through both the tza and Cl- bridging ligands to form a three-dimensional metal-organic framework (MOF). The compound has been found to exhibit blue photoluminescence in the solid state at room temperature and may be good candidates for photoactive materials. DSC thermal analysis shows the complex is an energetic coordination compound and tza can be used as an energetic ligand. © 2009 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | Foundation of Jiangsu Provincial Key Program of Physical Chemistry in Yangzhou University |
| Uncontrolled Keywords: | Lead(II) polymer; Crystal structure; Luminescence; Energetic compound |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 13 Jul 2020 08:32 |
| Last Modified: | 13 Jul 2020 08:32 |
| URI: | http://eprints.um.edu.my/id/eprint/25097 |
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